全文获取类型
收费全文 | 412篇 |
免费 | 10篇 |
国内免费 | 2篇 |
专业分类
化学 | 305篇 |
晶体学 | 3篇 |
力学 | 4篇 |
数学 | 41篇 |
物理学 | 71篇 |
出版年
2021年 | 2篇 |
2020年 | 9篇 |
2019年 | 7篇 |
2018年 | 8篇 |
2017年 | 3篇 |
2016年 | 5篇 |
2015年 | 5篇 |
2014年 | 4篇 |
2013年 | 20篇 |
2012年 | 23篇 |
2011年 | 27篇 |
2010年 | 11篇 |
2009年 | 6篇 |
2008年 | 18篇 |
2007年 | 27篇 |
2006年 | 23篇 |
2005年 | 17篇 |
2004年 | 30篇 |
2003年 | 18篇 |
2002年 | 16篇 |
2001年 | 9篇 |
2000年 | 6篇 |
1999年 | 8篇 |
1998年 | 2篇 |
1997年 | 1篇 |
1996年 | 3篇 |
1995年 | 5篇 |
1994年 | 3篇 |
1993年 | 2篇 |
1992年 | 3篇 |
1991年 | 5篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1988年 | 1篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 3篇 |
1984年 | 11篇 |
1983年 | 7篇 |
1982年 | 11篇 |
1981年 | 7篇 |
1980年 | 8篇 |
1979年 | 10篇 |
1978年 | 6篇 |
1977年 | 12篇 |
1976年 | 4篇 |
1975年 | 7篇 |
1974年 | 1篇 |
1973年 | 2篇 |
排序方式: 共有424条查询结果,搜索用时 421 毫秒
31.
32.
Fichele S Paley MN Woodhouse N Griffiths PD van Beek EJ Wild JM 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2004,167(1):1-11
Finite difference simulations have been used to model (3)He gas diffusion in simulated lung tissue. The technique has the advantage that a wide range of structural models and diffusion-sensitizing gradient waveforms can be investigated, for which analytical methods would otherwise be virtually impossible. Results from simulations and in vivo pulsed-gradient-spin-echo (PGSE) experiments show that the apparent diffusion coefficient (ADC) is a function of diffusion time and gradient strength, and suggests diffusion is locally anisotropic. The simulations have been compared to recent work on an analytical model that characterizes lung tissue as a series of independent cylinders. The results presented may have clinical implications for (3)He ADC measurements in assessing lung diseases such as chronic-obstructive-pulmonary-disease. 相似文献
33.
Action spectra are typically used as biological spectral weighting functions (BSWF) in biological research on the stratospheric ozone depletion issue. Despite their critical role in determining the amount of UV supplied in experiments, there has been only limited testing of different functions under realistic field conditions. Here, we calculate effective radiation according to five published BSWF and evaluate the appropriateness of these BSWF in representing the induction of UV-absorbing compounds. Experiments were carried out in the field using both ultraviolet-B radiation (280-320 nm) supplementation and selective filtering of solar UV radiation. For the four species tested, BSWF that extend into the ultraviolet-A radiation (320-400 nm) (UV-A) with moderate effectiveness best represented the observed results. When compared with the commonly used generalized plant response, these BSWF suggest that simulations of ozone depletion will require more radiation than in the past experiments. However, they imply lower radiation supplements than a new plant growth BSWF that has a greater emphasis on UV-A wavelengths. 相似文献
34.
Gago S Pillinger M Valente AA Santos TM Rocha J Gonçalves IS 《Inorganic chemistry》2004,43(17):5422-5431
A Zn,Al layered double hydroxide (LDH) with Zn/Al = 1.45 and containing nitrate anions was prepared by coprecipitation and characterized by powder X-ray diffraction, Zn K-edge extended X-ray absorption fine structure spectroscopy (EXAFS), thermogravimetric analysis, FTIR and FT Raman spectroscopy, and (27)Al MAS NMR spectroscopy. Three Zn...O and four Zn...M (M = Zn, Al) shells could be fitted to the low-temperature (40 K) EXAFS spectrum, in accordance with a model for an ordered cationic sheet. The nitrate anions were easily exchanged by 2,2'-bipyridine-5,5'-dicarboxylate anions, resulting in an increase in the basal spacing from 9 to 18 A. The basal spacing of the pillared derivative indicates that the anions are arranged with their longest dimension nearly perpendicular to the host layers. This material exhibits a high encapsulating ability, as evidenced by its interaction with a dichloromethane solution of the dioxomolybdenum(VI) complex MoO(2)Cl(2)(THF)(2). A material with a metal loading of 11.2 wt % was obtained. Molybdenum K-edge EXAFS analysis could not substantiate the formation of a supported complex of the type MoO(2)Cl(2)(N-N) but instead indicated the formation of unidentate-bridged entities of the type [O(2)Mo-O-MoO(2)] with a metal-metal separation of 3.29 A. The molybdenum-containing LDH was active as a catalyst for the liquid-phase epoxidation of cis-cyclooctene, 1-octene, and trans-2-octene using tert-butyl hydroperoxide as the oxygen source, yielding the corresponding epoxides as the only products. For reactions carried out with no additional solvent (other than n-decane) or in the presence of 1,2-dichloroethane, the solid catalyst could be recycled with no major loss of activity. Other tests confirmed that the systems functioned as true heterogeneous catalysts. 相似文献
35.
Hill M 《The Journal of the Acoustical Society of America》2003,114(5):2654-2661
Ultrasonic standing waves can be used to generate radiation forces on particles within a fluid. A number of authors have derived detailed representations of these forces but these are most commonly applied using an approximation to the energy distribution based upon an idealized standing wave within a mode based upon rigid boundaries. An electro-acoustic model of the acoustic energy distribution within a standing wave with arbitrary thickness boundaries has been expanded to model the radiation force on an example particle within the acoustic field. This is used to examine the force profile on a particle at resonances other than those predicted with rigid boundaries, and with pressure nodes at different positions. A simple analytical method for predicting modal conditions for combinations of frequencies and layer thickness characteristics is presented, which predicts that resonances can exist that will produce a pressure node at arbitrary positions in the fluid layer of such a system. This can be used to design resonators that will drive particles to positions other than the center of the fluid layer, including the fluid/solid boundary of the layer, with significant potential applications in sensing systems. Further, the model also predicts conditions for multiple subwavelength resonances within the fluid layer of a single resonator, each resonance having different nodal planes for particle concentration. 相似文献
36.
[structure: see text] Substitution of hydrogens by fluorines at the 5, 5', 6, 6', 7, 7', 8, and 8' positions of BINOL strongly affects distribution of electron density within the biaryl skeleton but has a very small influence on the torsion angle. The most important consequence of this structural alteration is the dramatic increase in configurational stability of homochiral F8BINOL. 相似文献
37.
38.
39.
In this short note a Tits alternative for certain kinds of groups which are residually of rank at mostr is obtained. The main theorem states that ifG is a group that is residually (locally (soluble-by-finite) of rankr), then eitherG is locally (soluble-by-finite) orG contains a non-abelian free subgroup.
The third author would like to thank the School of Mathematics at the University of Wales, Cardiff for its hospitality whild
part of this work was being done. 相似文献
40.